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MOF-74(Mg) Powder Metal Organic Frameworks (MOFs)

CAS: 1565828-96-7

MOF-74(Mg), with the formula C8H4O8Mg2 ,also written as: [Mg2(DHTA)2], the framework consists of magnesium ions coordinated to organic linkers, forming a porous structure that enables gas molecules to interact with the metal centers. The open metal sites in MOF-74(Mg) are particularly significant, as they enhance the adsorption of gases such as CO2, H2O, and H2 by providing strong interaction sites. 

 

    Model Number

    KAR-F56

    Product Name

    MOF-74(Mg)

    Particle size

    3-5μm

    Specific surface area

    ≥1100㎡/g

    Pore size

    1.2nm

    CO2 Adsorption
    One of the most widely studied applications of MOF-74(Mg) is its use in CO2 adsorption. The material exhibits excellent CO2 uptake, particularly at low pressures, due to the strong interaction between CO2 molecules and the open magnesium sites. This property makes MOF-74(Mg) a promising candidate for CO2 capture and storage (CCS) technologies. 

    Water Adsorption
    In addition to CO2 adsorption, MOF-74(Mg) has been investigated for its potential in water adsorption. The material exhibits a decent water uptake of 25.172 g/g at 1 bar, making it a promising candidate for atmospheric water harvesting (AWH). The adsorption process is influenced by the interaction between water molecules and the open metal sites, as well as the pore structure of the framework. 

    Electrochemical Applications
    MOF-74(Mg) has also been explored for its potential in electrochemical applications, particularly in solid-state electrolytes and batteries. The material's high ionic conductivity and stability make it an attractive candidate for use in all-solid-state sodium metal batteries (ASSMBs). When used as a solid electrolyte, MOF-74(Mg) exhibits an ionic conductivity of 8.53 × 10−4 S cm−1 at 70 °C, along with a wide potential window of 1-4.3 V. 

    Hydrogen Storage
    Hydrogen storage is another promising application of MOF-74(Mg). The material's open metal sites and porous structure enable strong interactions with hydrogen molecules, making it suitable for high-capacity hydrogen storage. When modified with defective frameworks and catalysts such as platinum (Pt), MOF-74(Mg) can achieve a reversible hydrogen storage capacity of 2.55 wt.% at 160 °C and 81 bar. This performance is further enhanced by the material's rapid hydrogen uptake/release and stable cycling capabilities. 

       KAR-F56 MOF-74(Mg)

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