China ZIF-8 Powder MOFs Suppliers - Mechanochemical Synthesis from Factory for Adsorption and Catalysis Applications

Structure and Stability of ZIF-8

ZIFs have advantages over zeolites such that the hybrid framework structures are expected to have more flexibility in surface modification. Among a large variety of ZIFs, ZIF-8 is the most representative one first synthesized by Chen’s group, and then systematically named by the Yaghi’s group. It can be fabricated by zinc and mIm with a sodalite structure consisting of a four- and a six-membered ring ZnN4 cluster, which has good thermal and chemical stability, especially large specific surface area, adjustable porosity and abundant active sites.

Applications and Membrane Performance

As we all know, ZIF-8 has shown up distinguished advantages and advances in adsorption, gas separation, drug delivery, catalysis and biosensor. ZIF-8 possesses the typical cubic sodalite topology with 11.6 Å large β-cages, which are connected by 6-membered ring windows (~3.4 Å). ZIF-8 and its membranes perform significant sieving advantages over ultramicroporous zeolites in selective separation of gas mixture contributing to the narrow six-membered ring pores (~3.4 Å) and hydrophobic behavior.